KEGG   ENZYME: 1.14.14.66
Entry
EC 1.14.14.66               Enzyme                                 
Name
marmesin synthase
Class
Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
Sysname
demethylsuberosin,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Reaction(IUBMB)
demethylsuberosin + [reduced NADPH---hemoprotein reductase] + O2 = (+)-marmesin + [oxidized NADPH---hemoprotein reductase] + H2O [RN:R08997]
Reaction(KEGG)
R08997
Substrate
demethylsuberosin [CPD:C18083];
[reduced NADPH---hemoprotein reductase] [CPD:C03024];
O2 [CPD:C00007]
Product
(+)-marmesin [CPD:C09276];
[oxidized NADPH---hemoprotein reductase] [CPD:C03161];
H2O [CPD:C00001]
Comment
A P-450 monoxygenase involved in psoralen biosynthesis, see EC 1.14.13.102, psoralen synthase.
History
EC 1.14.14.66 created 2018
Pathway
ec00999  Biosynthesis of various plant secondary metabolites
ec01110  Biosynthesis of secondary metabolites
Orthology
K25522  marmesin synthase
Reference
1  [PMID:2828055]
  Authors
Hamerski D, Matern U
  Title
Elicitor-induced biosynthesis of psoralens in Ammi majus L. suspension cultures.  Microsomal conversion of demethylsuberosin into (+)marmesin and psoralen.
  Journal
Eur J Biochem 171:369-75 (1988)
DOI:10.1111/j.1432-1033.1988.tb13800.x
Other DBs
ExplorEnz - The Enzyme Database: 1.14.14.66
IUBMB Enzyme Nomenclature: 1.14.14.66
ExPASy - ENZYME nomenclature database: 1.14.14.66
BRENDA, the Enzyme Database: 1.14.14.66

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