Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
BRITE hierarchy

linalool,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (8-hydroxylating)

linalool + 2 [reduced NADPH---hemoprotein reductase] + 2 O2 = (6E)-8-oxolinalool + 2 [oxidized NADPH---hemoprotein reductase] + 3 H2O (overall reaction) [RN:R09925];
(1a) linalool + [reduced NADPH---hemoprotein reductase] + O2 = (6E)-8-hydroxylinalool + [oxidized NADPH---hemoprotein reductase] + H2O [RN:R04366];
(1b) (6E)-8-hydroxylinalool + [reduced NADPH---hemoprotein reductase] + O2 = (6E)-8-oxolinalool + [oxidized NADPH---hemoprotein reductase] + 2 H2O [RN:R09924]

R04366 > R09922 R09923;
R09924 R09925
Reaction

linalool [CPD:C03985];
[reduced NADPH---hemoprotein reductase] [CPD:C03024];
O2 [CPD:C00007];
(6E)-8-hydroxylinalool [CPD:C04433]

A cytochrome P-450 (heme-thiolate) protein found in plants. The secondary electron donor is a specific [2Fe-2S] ferredoxin from the same bacterial strain.

EC 1.14.14.84 created 1989 as EC 1.14.99.28, transferred 2012 to EC 1.14.13.151, transferred 2018 to EC 1.14.14.84

1  [PMID:2295633]

2  [PMID:8376348]