KEGG   ENZYME: 2.3.1.213
Entry
EC 2.3.1.213                Enzyme                                 
Name
cyanidin 3-O-(6-O-glucosyl-2-O-xylosylgalactoside) 6'''-O-hydroxycinnamoyltransferase;
1-O-(4-hydroxycinnamoyl)-beta-D-glucose:cyanidin 3-O-(2"-O-xylosyl-6"-O-glucosylgalactoside) 6'''-O-(4-hydroxycinnamoyl)transferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
Sysname
1-O-(4-hydroxycinnamoyl)-beta-D-glucose:cyanidin 3-O-(6-O-beta-D-glucosyl-2-O-beta-D-xylosyl-beta-D-galactoside) 6'''-O-(4-hydroxycinnamoyl)transferase
Reaction(IUBMB)
1-O-(4-hydroxycinnamoyl)-beta-D-glucose + cyanidin 3-O-(6-O-beta-D-glucosyl-2-O-beta-D-xylosyl-beta-D-galactoside) = beta-D-glucose + cyanidin 3-O-[6-O-(6-O-4-hydroxycinnamoyl-beta-D-glucosyl)-2-O-beta-D-xylosyl-beta-D-galactoside] [RN:R10236]
Reaction(KEGG)
R10236
Substrate
1-O-(4-hydroxycinnamoyl)-beta-D-glucose [CPD:C16827];
cyanidin 3-O-(6-O-beta-D-glucosyl-2-O-beta-D-xylosyl-beta-D-galactoside) [CPD:C08612]
Product
beta-D-glucose [CPD:C00221];
cyanidin 3-O-[6-O-(6-O-4-hydroxycinnamoyl-beta-D-glucosyl)-2-O-beta-D-xylosyl-beta-D-galactoside] [CPD:C20460]
Comment
Isolated from the plant Daucus carota (Afghan cultivar carrot). In addition to 1-O-(4-hydroxycinnamoyl)-beta-D-glucose, the enzyme can use the 1-O-sinapoyl- and 1-O-feruloyl- derivatives of beta-D-glucose.
History
EC 2.3.1.213 created 2013
Reference
1  [PMID:24186789]
  Authors
Edgar Glassgen W, Ulrich Seitz H
  Title
Acylation of anthocyanins with hydroxycinnamic acids via 1-O-acylglucosides by protein preparations from cell cultures of Daucus carota L.
  Journal
Planta 186:582-5 (1992)
DOI:10.1007/BF00198039
Other DBs
ExplorEnz - The Enzyme Database: 2.3.1.213
IUBMB Enzyme Nomenclature: 2.3.1.213
ExPASy - ENZYME nomenclature database: 2.3.1.213
BRENDA, the Enzyme Database: 2.3.1.213

  All links  
Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (3)   
   KEGG REACTION (1)   
   KEGG RCLASS (2)   
All databases (7)   

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