KEGG   ENZYME: 2.3.1.90
Entry
EC 2.3.1.90                 Enzyme                                 
Name
beta-glucogallin O-galloyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
Sysname
1-O-galloyl-beta-D-glucose:1-O-galloyl-beta-D-glucose O-galloyltransferase
Reaction(IUBMB)
2 1-O-galloyl-beta-D-glucose = D-glucose + 1-O,6-O-digalloyl-beta-D-glucose [RN:R00049]
Reaction(KEGG)
R00049
Substrate
1-O-galloyl-beta-D-glucose [CPD:C01158]
Product
D-glucose [CPD:C00031];
1-O,6-O-digalloyl-beta-D-glucose [CPD:C04101]
Comment
beta-Glucogallin can act as donor and as acceptor. Digalloylglucose can also act as acceptor, with the formation of 1-O,2-O,6-O-trigalloylglucose
History
EC 2.3.1.90 created 1986
Reference
1  [PMID:24220744]
  Authors
Denzel K, Schilling G, Gross GG
  Title
Biosynthesis of gallotannins. Enzymatic conversion of 1,6-digalloylglucose to 1,2,6-trigalloylglucose.
  Journal
Planta 176:135-7 (1988)
DOI:10.1007/BF00392489
Reference
2
  Authors
Gross, G.G.
  Title
Synthesis of mono-galloyl-beta-D-glucose di-galloyl-beta-D-glucose and trigalloyl-beta-D-glucose by beta-glucogallin-dependent galloyltransferases from oak leaves.
  Journal
Z Natursforsch C: Biosci 38:519-523 (1983)
Other DBs
ExplorEnz - The Enzyme Database: 2.3.1.90
IUBMB Enzyme Nomenclature: 2.3.1.90
ExPASy - ENZYME nomenclature database: 2.3.1.90
BRENDA, the Enzyme Database: 2.3.1.90
CAS: 87502-55-4

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