KEGG   ENZYME: 2.4.1.104
Entry
EC 2.4.1.104                Enzyme                                 
Name
o-dihydroxycoumarin 7-O-glucosyltransferase;
uridine diphosphoglucose-o-dihydroxycoumarin 7-O-glucosyltransferase;
UDP-glucose:o-dihydroxycoumarin glucosyltransferase
Class
Transferases;
Glycosyltransferases;
Hexosyltransferases
Sysname
UDP-glucose:7,8-dihydroxycoumarin 7-O-beta-D-glucosyltransferase
Reaction(IUBMB)
UDP-glucose + 7,8-dihydroxycoumarin = UDP + daphnin [RN:R03548]
Reaction(KEGG)
R03548
Substrate
UDP-glucose [CPD:C00029];
7,8-dihydroxycoumarin [CPD:C03093]
Product
UDP [CPD:C00015];
daphnin [CPD:C01421]
Comment
Converts the aglycone daphetin into daphnin and, more slowly, esculetin into cichoriin, umbelliferone into skimmin, hydrangetin into hydrangin and scopoletin into scopolin.
History
EC 2.4.1.104 created 1983
Reference
1
  Authors
Ibrahim, R.K. and Boulay, B.
  Title
Purification and some properties of UDP-glucose:o-hydroxycoumarin 7-O-glucosyltransferase from tobacco cell cultures.
  Journal
Plant Sci Lett 18:177-184 (1980)
Other DBs
ExplorEnz - The Enzyme Database: 2.4.1.104
IUBMB Enzyme Nomenclature: 2.4.1.104
ExPASy - ENZYME nomenclature database: 2.4.1.104
BRENDA, the Enzyme Database: 2.4.1.104
CAS: 74114-37-7

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