KEGG   ENZYME: 2.4.1.247
Entry
EC 2.4.1.247                Enzyme                                 
Name
beta-D-galactosyl-(1->4)-L-rhamnose phosphorylase;
D-galactosyl-beta1->4-L-rhamnose phosphorylase;
GalRhaP
Class
Transferases;
Glycosyltransferases;
Hexosyltransferases
Sysname
beta-D-galactosyl-(1->4)-L-rhamnose:phosphate 1-alpha-D-galactosyltransferase
Reaction(IUBMB)
beta-D-galactosyl-(1->4)-L-rhamnose + phosphate = L-rhamnose + alpha-D-galactose 1-phosphate [RN:R09632]
Reaction(KEGG)
R09632
Substrate
beta-D-galactosyl-(1->4)-L-rhamnose [CPD:C19758];
phosphate [CPD:C00009]
Product
L-rhamnose [CPD:C00507];
alpha-D-galactose 1-phosphate [CPD:C00446]
Comment
The enzyme from Clostridium phytofermentans is also active towards towards beta-D-galactosyl derivatives of L-mannose, L-lyxose, D-glucose, 2-deoxy-D-glucose, and D-galactose in this order. Differs from 1,3-beta-galactosyl-N-acetylhexosamine phosphorylase (EC 2.4.1.211) in being active towards L-rhamnose and inactive towards N-acetyl hexosamine derivatives.
History
EC 2.4.1.247 created 2009
Orthology
K15534  beta-D-galactosyl-(1->4)-L-rhamnose phosphorylase
Genes
PPM: PPSC2_04505(M1-1040)
PPO: PPM_0844(M1-1040)
PPOL: X809_04085
PPQ: PPSQR21_009000
PPOY: RE92_07460
PBD: PBOR_04085
POD: PODO_03630
PAEN: P40081_04395
PAEF: R50345_03490
PAEQ: R50912_04000
PAEA: R70723_03420
PAEE: R70331_03425
PAEH: H70357_03775
PAEJ: H70737_03770
PPEO: ABE82_04240
PXL: BS614_07860
PDH: B9T62_36785(gnpA)
PBAC: HUB98_21325(gnpA)
PTJ: JRJ22_03000(gnpA)
PMAH: PTQ21_09195(gnpA)
PAMY: P9222_00440
PPOG: QPK24_03450(gnpA)
PPAB: KET34_04340(gnpA)
CEU: A7L45_08570
HHJ: NQ487_22465(gnpA)
CSS: Cst_c00210
CSD: Clst_0021
CBAF: JS518_09230(gnpA)
BPB: bpr_I0232
BHU: bhn_I2549
CPY: Cphy_1920
LXA: OW255_15745(gnpA)
ACEL: acsn021_40080(lnbP)
SSUN: H9Q77_06360(gnpA)
XYL: ET495_16735(gnpA)
TDF: H9L22_15760(gnpA)
OTE: Oter_1377
OLE: K0B96_10400(gnpA)
ELUT: CKA38_00095(gnpA)
VBA: IMCC26134_08930
SBU: SpiBuddy_0363
SASS: MUG09_01975(gnpA)
 » show all
Reference
1  [PMID:19491100]
  Authors
Nakajima M, Nishimoto M, Kitaoka M
  Title
Characterization of three beta-galactoside phosphorylases from Clostridium phytofermentans: discovery of d-galactosyl-beta1->4-l-rhamnose phosphorylase.
  Journal
J Biol Chem 284:19220-7 (2009)
DOI:10.1074/jbc.M109.007666
  Sequence
[cpy:Cphy_1920]
Other DBs
ExplorEnz - The Enzyme Database: 2.4.1.247
IUBMB Enzyme Nomenclature: 2.4.1.247
ExPASy - ENZYME nomenclature database: 2.4.1.247
BRENDA, the Enzyme Database: 2.4.1.247
CAS: 1236189-79-9

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Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (2)   
   KEGG REACTION (1)   
   KEGG RCLASS (1)   
Gene (509)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (42)   
   KEGG MGENES (466)   
Protein sequence (45)   
   UniProt (44)   
   SWISS-PROT (1)   
DNA sequence (16)   
   GenBank (8)   
   EMBL (8)   
Protein domain (6)   
   InterPro (6)   
All databases (582)   

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