KEGG   ENZYME: 4.2.3.105
Entry
EC 4.2.3.105                Enzyme                                 
Name
tricyclene synthase;
TPS3
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
geranyl-diphosphate diphosphate-lyase (cyclizing; tricyclene-forming)
Reaction(IUBMB)
geranyl diphosphate = tricyclene + diphosphate [RN:R09961]
Reaction(KEGG)
R09961
Substrate
geranyl diphosphate [CPD:C00341]
Product
tricyclene [CPD:C20241];
diphosphate [CPD:C00013]
Comment
The enzyme from Solanum lycopersicum (tomato) gives a mixture of tricyclene, camphene, beta-myrcene, limonene, and traces of several other monoterpenoids. See EC 4.2.3.117. (-)-camphene synthase, EC 4.2.3.15, myrcene synthase and EC 4.2.3.16, (4S)-limonene synthase.
History
EC 4.2.3.105 created 2012
Orthology
K21925  (-)-camphene/tricyclene/(4S)-limonene/myrcene synthase
Genes
SLY101245212(TPS3) 101249864
SPEN107012939 107012948
SOT102591915 102602070
SSTN125861389 125861571
CANN107840093
LBB132598839
NTA107785945 107787835
NSY104238653
NTO104090536
NAU109214608
SSPL121755010
SMIL131005775 131026618 131026619
SHIS125185612 125185636 125193586 125197284 125200997 125204274 125208619 125218604 125219856 125220542 125224358
 » show all
Reference
1  [PMID:21813655]
  Authors
Falara V, Akhtar TA, Nguyen TT, Spyropoulou EA, Bleeker PM, Schauvinhold I, Matsuba Y, Bonini ME, Schilmiller AL, Last RL, Schuurink RC, Pichersky E
  Title
The tomato terpene synthase gene family.
  Journal
Plant Physiol 157:770-89 (2011)
DOI:10.1104/pp.111.179648
  Sequence
[sly:101245212]
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.105
IUBMB Enzyme Nomenclature: 4.2.3.105
ExPASy - ENZYME nomenclature database: 4.2.3.105
BRENDA, the Enzyme Database: 4.2.3.105

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