KEGG   ENZYME: 4.2.3.177
Entry
EC 4.2.3.177                Enzyme                                 
Name
beta-thujene synthase;
CoTPS1
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
geranyl-diphosphate diphosphate-lyase (cyclizing, beta-thujene-forming)
Reaction(IUBMB)
geranyl diphosphate = beta-thujene + diphosphate [RN:R11842]
Reaction(KEGG)
R11842
Substrate
geranyl diphosphate [CPD:C00341]
Product
beta-thujene [CPD:C21702];
diphosphate [CPD:C00013]
Comment
Isolated from the plant Cananga odorata var. fruticosa (ylang ylang). The enzyme forms roughly equal proportions of beta-thujene, sabinene, beta-pinene and alpha-terpinene see EC 4.2.3.109/EC 4.2.3.110 sabinene synthase, EC 4.2.3.120/EC 4.2.3.122 beta-pinene synthase, EC 4.2.3.115 alpha-terpinene synthase.
History
EC 4.2.3.177 created 2017
Reference
1  [PMID:25956881]
  Authors
Jin J, Kim MJ, Dhandapani S, Tjhang JG, Yin JL, Wong L, Sarojam R, Chua NH, Jang IC
  Title
The floral transcriptome of ylang ylang (Cananga odorata var. fruticosa) uncovers biosynthetic pathways for volatile organic compounds and a multifunctional and novel sesquiterpene synthase.
  Journal
J Exp Bot 66:3959-75 (2015)
DOI:10.1093/jxb/erv196
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.177
IUBMB Enzyme Nomenclature: 4.2.3.177
ExPASy - ENZYME nomenclature database: 4.2.3.177
BRENDA, the Enzyme Database: 4.2.3.177

  All links  
Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (1)   
   KEGG REACTION (1)   
Protein sequence (2)   
   UniProt (1)   
   SWISS-PROT (1)   
Protein domain (7)   
   InterPro (7)   
All databases (13)   

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