KEGG   ENZYME: 4.2.3.197
Entry
EC 4.2.3.197                Enzyme                                 
Name
eudesmane-5,11-diol synthase;
ZmEDS (gene name)
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, 7-epi-ent-eudesmane-5,11-diol-forming)
Reaction(IUBMB)
(2E,6E)-farnesyl diphosphate + 2 H2O = 7-epi-ent-eudesmane-5,11-diol + diphosphate [RN:R12259]
Reaction(KEGG)
R12259
Substrate
(2E,6E)-farnesyl diphosphate [CPD:C00448];
H2O [CPD:C00001]
Product
7-epi-ent-eudesmane-5,11-diol [CPD:C22043];
diphosphate [CPD:C00013]
Comment
Isolated from the plant Zea mays (maize). The product is named in the reference using a different numbering scheme for eudesmane.
History
EC 4.2.3.197 created 2018
Orthology
K23754  eudesmane-5,11-diol synthase
Genes
OSA4332889 4332895 9272299
DOSAOs03t0361100-00(Os03g0361100) Os03t0361600-00(Os03g0361600) Os03t0361700-00(Os03g0361700) Os03t0362500-00(Os03g0362500)
OBR102708323
OGL127765473 127765474 127765475 127765476 127766255 127767949
BDI100837490
ATS109754902 109774711
TDC119270962 119279075 119281968 119281970 119298457
TAES123066184 123066185 123076817 123076819 123108406
TUA125511462 125529558 125546462 125552526
LPER127338335
LRD124663865 124664207 124664526 124681736
SBI8060579 8064774 8065973 8080793 8083139
ZMA100281754 103640304 103646867
SITA101755067 101756327 101756584 101765119
SVS117833555 117865138
PVIR120652279 120690259 120690260
PHAI112872404 112901180 112903757
 » show all
Reference
1  [PMID:29570233]
  Authors
Liang J, Liu J, Brown R, Jia M, Zhou K, Peters RJ, Wang Q
  Title
Direct production of dihydroxylated sesquiterpenoids by a maize terpene synthase.
  Journal
Plant J 94:847-856 (2018)
DOI:10.1111/tpj.13901
  Sequence
[zma:100281754]
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.197
IUBMB Enzyme Nomenclature: 4.2.3.197
ExPASy - ENZYME nomenclature database: 4.2.3.197
BRENDA, the Enzyme Database: 4.2.3.197

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