KEGG   ENZYME: 4.2.3.209
Entry
EC 4.2.3.209                Enzyme                                 
Name
(R)-axinyssene synthase;
CysTC2
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
geranylgeranyl-diphosphate diphosphate-lyase [(R)-axinyssene-forming]
Reaction(IUBMB)
geranylgeranyl diphosphate = (R)-axinyssene + diphosphate [RN:R13102]
Reaction(KEGG)
R13102
Substrate
geranylgeranyl diphosphate [CPD:C00353]
Product
(R)-axinyssene [CPD:C22615];
diphosphate [CPD:C00013]
Comment
Requires Mg2+. Characterized from the bacterium Archangium violaceum.
History
EC 4.2.3.209 created 2022
Orthology
K26353  (R)-axinyssene synthase
Genes
AGEAA314_00398
AVMJQX13_14860
CHORMKQ68_04505
Reference
1  [PMID:28371074]
  Authors
Yang YL, Zhang S, Ma K, Xu Y, Tao Q, Chen Y, Chen J, Guo S, Ren J, Wang W, Tao Y, Yin WB, Liu H.
  Title
Discovery and Characterization of a New Family of Diterpene Cyclases in Bacteria and Fungi.
  Journal
Angew Chem Int Ed Engl 56:4749-4752 (2017)
DOI:10.1002/anie.201700565
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.209
IUBMB Enzyme Nomenclature: 4.2.3.209
ExPASy - ENZYME nomenclature database: 4.2.3.209
BRENDA, the Enzyme Database: 4.2.3.209

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