KEGG   ENZYME: 4.2.3.215
Entry
EC 4.2.3.215                Enzyme                                 
Name
delta-araneosene synthase
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
geranylgeranyl-diphosphate diphosphate-lyase [cyclizing, delta-araneosene-forming]
Reaction(IUBMB)
geranylgeranyl diphosphate = delta-araneosene + diphosphate [RN:R13230]
Reaction(KEGG)
R13230
Substrate
geranylgeranyl diphosphate [CPD:C00353]
Product
delta-araneosene [CPD:C22839];
diphosphate [CPD:C00013]
Comment
Isolated from the fungus Colletotrichum gloeosporioidea. delta-Araneosene may be involved in the biosynthesis of dolasta-1(15),8-diene (see EC 4.2.3.214, dolasta-1(15),8-diene synthase) and cycloaraneosene (see EC 4.2.3.191, cycloaraneosene synthase).
History
EC 4.2.3.215 created 2023
Orthology
K27203  dolasta-1(15),8-diene / delta-araneosene synthase
Genes
MGR: MGG_07506
PGRI: PgNI_04844
CHIG: CH63R_06464
Reference
1  [PMID:30277637]
  Authors
Bian G, Rinkel J, Wang Z, Lauterbach L, Hou A, Yuan Y, Deng Z, Liu T, Dickschat JS.
  Title
A Clade II-D Fungal Chimeric Diterpene Synthase from Colletotrichum gloeosporioides Produces Dolasta-1(15),8-diene.
  Journal
Angew Chem Int Ed Engl 57:15887-15890 (2018)
DOI:10.1002/anie.201809954
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.215
IUBMB Enzyme Nomenclature: 4.2.3.215
ExPASy - ENZYME nomenclature database: 4.2.3.215
BRENDA, the Enzyme Database: 4.2.3.215

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Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (1)   
   KEGG REACTION (1)   
Gene (4)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (3)   
All databases (8)   

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