Entry Name Class Isomerases;BRITE hierarchy
Sysname geraniol hydroxymutase
Reaction(IUBMB) geraniol = (3S)-linalool [RN:
R09708 ]
Reaction(KEGG) Substrate Product Comment In absence of oxygen the bifunctional linalool dehydratase-isomerase can catalyse in vitro two reactions, the isomerization of (3S)-linalool to geraniol and the hydration of myrcene to (3S)-linalool, the latter activity being classified as EC
4.2.1.127 , linalool dehydratase.
History EC 5.4.4.4 created 2011, modified 2012
Pathway ec01110 Biosynthesis of secondary metabolites
Orthology K20614 linalool dehydratase / geraniol isomerase
Genes Taxonomy Reference Authors Brodkorb D, Gottschall M, Marmulla R, Luddeke F, Harder J
Title Linalool dehydratase-isomerase, a bifunctional enzyme in the anaerobic degradation of monoterpenes.
Journal Sequence Reference Authors Luddeke F, Harder J
Title Enantiospecific (S)-(+)-linalool formation from beta-myrcene by linalool dehydratase-isomerase.
Journal Sequence Other DBs ExplorEnz - The Enzyme Database: 5.4.4.4
ExPASy - ENZYME nomenclature database: 5.4.4.4
BRENDA, the Enzyme Database: 5.4.4.4
