KEGG   ENZYME: 1.3.99.25
Entry
EC 1.3.99.25                Enzyme                                 
Name
carvone reductase
Class
Oxidoreductases;
Acting on the CH-CH group of donors;
With unknown physiological acceptors
Sysname
(+)-dihydrocarvone:acceptor 1,6-oxidoreductase
Reaction(IUBMB)
(1) (+)-dihydrocarvone + acceptor = (-)-carvone + reduced acceptor [RN:R06373];
(2) (-)-isodihydrocarvone + acceptor = (+)-carvone + reduced acceptor [RN:R06372]
Reaction(KEGG)
R06372 R06373
Substrate
(+)-dihydrocarvone;
acceptor [CPD:C00028];
(-)-isodihydrocarvone
Product
(-)-carvone [CPD:C01767];
reduced acceptor [CPD:C00030];
(+)-carvone [CPD:C11383]
Comment
This enzyme participates in the carveol and dihydrocarveol degradation pathway of the Gram-positive bacterium Rhodococcus erythropolis DCL14. The enzyme has not been purified, and requires an unknown cofactor, which is different from NAD+, NADP+ or a flavin.
History
EC 1.3.99.25 created 2008
Pathway
ec00903  Limonene degradation
ec01120  Microbial metabolism in diverse environments
Reference
1  [PMID:10832640]
  Authors
van der Werf MJ, Boot AM
  Title
Metabolism of carveol and dihydrocarveol in Rhodococcus erythropolis DCL14.
  Journal
Microbiology 146 ( Pt 5):1129-41 (2000)
DOI:10.1099/00221287-146-5-1129
Other DBs
ExplorEnz - The Enzyme Database: 1.3.99.25
IUBMB Enzyme Nomenclature: 1.3.99.25
ExPASy - ENZYME nomenclature database: 1.3.99.25
BRENDA, the Enzyme Database: 1.3.99.25

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