KEGG   ENZYME: 4.2.3.80
Entry
EC 4.2.3.80                 Enzyme                                 
Name
alpha-longipinene synthase
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (alpha-longipinene-forming)
Reaction(IUBMB)
(2E,6E)-farnesyl diphosphate = alpha-longipinene + diphosphate [RN:R10726]
Reaction(KEGG)
R10726
Substrate
(2E,6E)-farnesyl diphosphate [CPD:C00448]
Product
alpha-longipinene [CPD:C20804];
diphosphate [CPD:C00013]
Comment
The enzyme from Norway spruce produces longifolene as the main product (cf. EC 4.2.3.58, longifolene synthase). alpha-Longipinene constitutes about 15% of the total products.
History
EC 4.2.3.80 created 2011
Orthology
K14185  longifolene/alpha-longipinene synthase
Reference
1  [PMID:15310829]
  Authors
Martin DM, Faldt J, Bohlmann J
  Title
Functional characterization of nine Norway Spruce TPS genes and evolution of gymnosperm terpene synthases of the TPS-d subfamily.
  Journal
Plant Physiol 135:1908-27 (2004)
DOI:10.1104/pp.104.042028
  Sequence
[ag:AAS47695]
Reference
2  [PMID:18493792]
  Authors
Kopke D, Schroder R, Fischer HM, Gershenzon J, Hilker M, Schmidt A
  Title
Does egg deposition by herbivorous pine sawflies affect transcription of sesquiterpene synthases in pine?
  Journal
Planta 228:427-38 (2008)
DOI:10.1007/s00425-008-0747-8
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.80
IUBMB Enzyme Nomenclature: 4.2.3.80
ExPASy - ENZYME nomenclature database: 4.2.3.80
BRENDA, the Enzyme Database: 4.2.3.80

  All links  
Chemical substance (3)   
   KEGG COMPOUND (3)   
Chemical reaction (2)   
   KEGG REACTION (1)   
   KEGG RCLASS (1)   
Gene (2)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (1)   
Protein sequence (2)   
   UniProt (1)   
   SWISS-PROT (1)   
Protein domain (8)   
   InterPro (8)   
All databases (17)   

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